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Single Phase
Single phase wiring will change as follows:
Red (Live) becomes Brown
Black (Neutral) becomes Blue
3 Phase
3 phase wiring will change as follows:
Red (Phase 1) becomes Brown
Yellow (Phase 2) becomes Black
Blue (Phase 3) becomes Grey
Black (Neutral) becomes Blue
Earth remains the Green/Yellow that it is today.
Needless to say that the consequences of getting it wrong can be disasterous.
Safe working practises for working with the new cables include, extra training, updating of records and manuals etc.
Warning notices and extra labelling may also be required, check the link below for details.
Below is a diagram to help you:

You should also visit IEE for more details.
